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It turns out that when the polygon has an odd number of sides, the largest small polygon is always a regular polygon. So the largest small triangle is an equilateral triangle, the largest small pentagon has five equal sides and angles, and so forth. But the largest small hexagon is not an equilateral hexagon! You can find a picture of it at MathWorld, see an animation of its rotations at the delightfully old-fashioned website Hall of Hexagons, or read Ron Graham's original paper, which involves an argument via the excellently named (by Conway, unsurprisingly) thrackleations.
The largest small octagons, 10-gons, and 12-gons have also been identified, but for even-sided polygons with 14 or more sides, finding the best one is still an open problem.
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